Season
- Season 1 2013-04-15
Episode
- Episode 1: Revolutionary Transfer Student
- Episode 2: Beyond 666
- Episode 3: L-Elf's Prophecy
- Episode 4: The Valvrave is the Hostage
- Episode 5: The Sakimori Academy Sings
- Episode 6: Saki's Comeback
- Episode 7: Haruto Under the Ruins
- Episode 8: Princess of Light
- Episode 9: Dog and Thunder
- Episode 10: Campaign Promise of Love
- Episode 11: Military Tribunal #54
- Episode 12: The Heretic Activates
- Episode 13: A Cursed Bond
- Episode 14: Siblings of the Atmosphere
- Episode 15: Return to Karlstein
- Episode 16: Marie Set Free
- Episode 17: The Rune Abyss
- Episode 18: A Father's Wish
- Episode 19: Sadness is Like the Falling Snow
- Episode 20: The Kamitsuki Exposed
- Episode 21: The Cost of Lies
- Episode 22: Fist of the Moon
- Episode 23: The Operation to Retake Module 77
- Episode 24: Revolution to the Future
Valvrave the Liberator Season 1 The Sakimori Academy Sings
Haruto Tokishima, a student from Sakimori High School living on the sphere's "Module 77", discovers a mysterious and powerful mecha called Valvrave (ヴァルヴレイヴ Varuvureivu?) and uses it to defend the module from a Dorssian invasion that takes over the rest of JIOR. Once they learn that both Dorssia and the ARUS intend to claim the Valvrave for themselves, with no concern with their lives, the students of Sakimori High declare Module 77 an independent state and abandon JIOR territory. Soon after, several other Valvraves are found inside the school and some of them are claimed by other students who join Haruto's fight to protect it. Once Haruto is approached by L-elf Karlstein, a Dorssian spy who claims to have the intentions to one day stage a revolution in his own country, both join forces in an unlikely alliance to secure the sovereignty of their newfound nation declared and officially recognized as New JIOR.
